Asymmetric aziridination: a new entry to optically active non-N-protected aziridines

【2003年】

◆(NO)Ru(salen)-catalyzed Aerobic Oxidation of o-Hydroxybenzyl Alcohol Derivatives.
A. Tashiro, A. Mitsuishi, R. Irie, and T. Katsuki,
Synlett, 2003, (12), 1868-1870.

◆Asymmetric Intramolecular Allylic Amination: Straightforward Approach to Chiral C1-Substituted Tetrahydroisoquinolines.
K. Ito, S. Akashi, B. Saito, and T. Katsuki,
Synlett, 2003, (12), 1809-1812.
　
◆Highly Enantioselective Cr(salen)-Catalyzed Reaction of 2-(Trimethylsilyloxy)furan and Aldehydes. Effect of Alcohol on Enantioselectivity.
S. Onitsuka, Y. Matsuoka, R. Irie, and T. Katsuki,
Chem. Lett., 32 (10), 974-975 (2003).

◆Mechanism of Asymmetric Sulfimidation with N-Alkoxycarbonyl Azide in the Presence of (OC)Ru(salen) Complex.
T. Uchida, Y. Tamura, M. Ohba, and T. Katsuki,
Tetrahedron Lett., 44 (43), 7965-7968 (2003).

◆Enantioselective Addition of 2-(Trimethylsilyloxy)furan to Aldehydes Using Cr(salen) as Catalyst. Effect of Water on Enantioselectivity.
Y. Matsuoka, R. Irie, and T. Katsuki,
Chem. Lett., 32 (7), 584-585 (2003).

◆(Salen)ruthenium-catalyzed Desymmetrization of Meso-diols (2). Apical Ligand Effect on Enantioselectivity.
H. Shimizu and T. Katsuki,
Chem. Lett., 32 (6), 480-481 (2003).

◆Nb(salen)-catalyzed Sulfoxidation.
T. Miyazaki and T. Katsuki,
Synlett, 2003, (7), 1046-1048.

◆Asymmetric Baeyer-Villiger Oxidation of Prochiral Cyclobutanones Using a Chiral Cationic Palladium(II) 2-(Phosphinophenyl)pyridine Complex as Catalyst.
K. Ito, A. Ishii, T. Kuroda, and T. Katsuki,
Synlett, 2003, (5), 643-646.

◆Enantioselective Aziridination and Amination Using p-Toluenesulfonyl Azide in the Presence of Ru(salen)(CO) Complex.
K. Omura, M. Murakami, T. Uchida, R. Irie, and T. Katsuki,
Chem. Lett., 32 (4), 354-355 (2003).

◆Asymmetric Intramolecular Cyclopropanation of Diazo Compounds with Metallosalen Complexes as Catalyst: Structural Tuning of Salen Ligand.
B. Saha, T. Uchida, and T. Katsuki,
Tetrahedron: Asymmetry, 14 (7), 823-836 (2003).

◆Highly Enantioselective (OC)Ru(salen)-catalyzed Sulfimidation Using N-Alkoxycarbonyl Azide as Nitrene Precursor.
Y. Tamura, T. Uchida, and T. Katsuki,
Tetrahedron Lett., 44 (16), 3301-3303 (2003).

◆Ru(salen)-catalyzed Asymmetric Sulfimidation and Subsequent [2,3]Sigmatropic Rearrangement.
M. Murakami, T. Uchida, B. Saito, and T. Katsuki,
Chirality, 15 (2), 116-123 (2003).

◆Asymmetric Oxidation of Racemic 2-Substituted 1,3-Oxathianes.
B. Saito and T. Katsuki,
Chirality, 15 (1), 24-27 (2003).

■Some Recent Advances in Metallosalen Chemistry.
T. Katsuki,
Synlett, 2003, (3), 281-297.

【2002年】

◆Highly Diastereo- and Enantioselective Aziridination of α,β-Unsaturated Amides with Diaziridine and Mechanistic Consideration on Its Stereochemistry.
H. Ishihara, K. Hori, H. Sugihara, Y. N. Ito, and T. Katsuki,
Helv. Chim. Acta, 85 (12), 4272-4286 (2002).

◆New Asymmetric Catalysis by (Salen)cobalt(III) Complexes (salen = [Bis(salicylidene)ethylenediaminato] = {{2,2'-[ethane-1,2-diyl]bis[(nitrilo-κN)methylidyne]bis[phenolato-κO]}(2-)}) of Cis-β-structure: Enantioselective Baeyer-Villiger Oxidation of Prochiral Cyclobutanones.
T. Uchida, T. Katsuki, K. Ito, S. Akashi, A. Ishii, and T. Kuroda,
Helv. Chim. Acta, 85 (10), 3078-3089 (2002).

◆(Salen)ruthenium-catalyzed Desymmetrization of Meso-diols: Catalytic Aerobic Asymmetric Oxidation under Photo-irradiation.
H. Shimizu, K. Nakata, and T. Katsuki,
Chem. Lett. 2002, (11), 1080-1081.

◆Highly Enantioselective Intramolecular Cyclopropanation of Alkenyl Diazo Ketones Using Ru(salen) as Catalyst.
B. Saha, T. Uchida, and T. Katsuki,
Chem. Lett., 2002, (8), 846-847.

◆Stereocontrolled OH Protection: Asymmetric Tetrahydrofuranylation.
H. Nagano and T. Katsuki,
Chem. Lett., 2002, (8), 782-783.

◆Highly Enantioselective Baeyer-Villiger Oxidation Using Zr(salen) Complex as Catalyst.
A. Watanabe, T. Uchida, K. Ito, and T. Katsuki,
Tetrahedron Lett., 43 (25), 4481-4485 (2002).

◆Chiral (OC)Ru(salen)-catalyzed Tandem Sulfimidation and [2,3]Sigmatropic Rearrangement: Asymmetric C-N Bond Formation.
M. Murakami and T. Katsuki,
Tetrahedron Lett., 43 (21), 3947-3949 (2002).

◆Catalytic Aerobic Oxidation of Diols under Photoirradiation: Highly Efficient Synthesis of Lactols.
A. Miyata, M. Furukawa, R. Irie, and T. Katsuki,
Tetrahedron Lett., 43 (19), 3481-3484 (2002).

◆Highly Enantioselective Oxidation of Cyclic Dithioacetals by Using a Ti(salen) and Urea・Hydrogen Peroxide System.
T. Tanaka, B. Saito, and T. Katsuki,
Tetrahedron Lett., 43 (18), 3259-3262 (2002).

◆Asymmetric Cyclization via Oxygen Cation Radical: Enantioselective Synthesis of Cis-4b,9b-dihydrobenzofuro[3,2-b]benzofurans.
K. Masutani, R. Irie, and T. Katsuki,
Chem. Lett., 2002, (1), 36-37.

◆Vanadium-catalyzed Enantioselective Sulfoxidation of Methyl Aryl Sulfides with Hydrogen Peroxide as Terminal Oxidant.　
C. Ohta, H. Shimizu, A. Kondo, and T. Katsuki,
Synlett, 2002, (1), 161-163.

■Asymmetric Oxidation Reactions.
T. Katsuki, Editor.,
UK. (2001), 244 pp. Publisher: (Oxford University Press, Oxford, UK) Book

■Chiral Metallosalen Complexes: Structures and Catalyst Tuning for Asymmetric Epoxidation and Cyclopropanation.
T. Katsuki,
Adv. Syn. Cat., 344 (2), 131-147 (2002).

【2001年】

◆Mechanistic Consideration of Ti(salen)-catalyzed Asymmetric Sulfoxidation.
B. Saito and T. Katsuki,
Tetrahedron Lett. 42 (47), 8333-8336 (2001).

◆Highly Diastereoselective Aziridination of α,β-Unsaturated Amides Using Diaziridine.
H. Ishihara, Y. N. Ito, and T. Katsuki,
Chem. Lett. 2001, (10), 984-985.

◆Asymmetric Epoxidation with a Photoactivated [Ru(salen)] Complex.
K. Nakata, T. Takeda, J. Mihara, T. Hamada, R. Irie, and T. Katsuki,
Chem. Eur. J., 7 (17), 3776-3782 (2001).

◆Ru(salen)-Catalyzed Asymmetric Sulfimidation Using Arylsulfonyl Azide.
M. Murakami, T. Uchida, and T. Katsuki,
Tetrahedron Lett. 42 (40), 7071-7074 (2001).

◆Chemoselective Aerobic Oxidation of Primary Alcohols Catalyzed by a Ruthenium Complex.
A. Miyata, M. Murakami, R. Irie, and T. Katsuki,
Tetrahedron Lett., 42 (40), 7067-7070 (2001).

◆Cationic Co(III)(salen)-catalyzed Enantioselective Baeyer-Villiger Oxidation of 3-Arylcyclobutanones Using Hydrogen Peroxide as a Terminal Oxidant.
T. Uchida and T. Katsuki,
Tetrahedron Lett., 42 (39), 6911-6914 (2001).

◆Mn(salen)-catalyzed Sulfimidation: What Are the Real Active Species in Sulfimidation?
C. Ohta and T. Katsuki,
Tetrahedron Lett., 42 (23), 3885-3888 (2001).

◆Ti(salen)-catalyzed Enantioselective Sulfoxidation Using Hydrogen Peroxide as a Terminal Oxidant.
B. Saito and T. Katsuki,
Tetrahedron Lett., 42 (23), 3873-3876 (2001).

◆Mn(salen)-catalyzed Enantioselective C-H Amination.
Y. Kohmura and T. Katsuki,
Tetrahedron Lett., 42 (19), 3339-3342 (2001).

◆Co(II)-salen-catalyzed Asymmetric Intramolecular Cyclopropanation.
T. Uchida, B. Saha, and T. Katsuki,
Tetrahedron Lett., 42 (13), 2521-2524 (2001).

◆2-(Phosphinoaryl)pyridine Ligand (2): Symmetric Allylic Alkylation of 2-Cycloalkenyl Carboxylate.
K. Ito, R. Kashiwagi, S. Hayashi, T. Uchida, and T. Katsuki,
Synlett, 2001, (2), 284-286.

◆Highly Enantioselective Cyclopropanation with Co(II)-salen Complexes: Control of cis- and trans-Selectivity by Rational Ligand Design.
T. Niimi, T. Uchida, R. Irie, and T. Katsuki,
Adv. Synth. Cat., 343 (1), 79-88 (2001).

◆Asymmetric Hetero Diels-Alder Reaction Using Chiral Cationic Metallosalen Complexes as Catalysts.
K. Aikawa, R. Irie, and T. Katsuki,
Tetrahedron, 57 (5), 845-851 (2001).

◆Lewis Acid Catalysis of Second-generation Metallosalen Complexes: An Explanation for Stereochemistry of Asymmetric Hetero Diels-Alder Reaction.
J. Mihara, K. Aikawa, T. Uchida, R. Irie, and T. Katsuki,
Heterocycles, 54(1), 395-404 (2001).

◆Intramolecular Asymmetric Cyclopropanation with (Nitroso)(salen)ruthenium(II) Complexes as Catalysts.
B. Saha, T. Uchida, and T. Katsuki,
Synlett, 2001, (1), 114-116.

■The Catalytic Enantioselective Synthesis of 0ptically Active Epoxides and Tetrahydrofurans. Asymmetric Epoxidation, the Desymmetrization of Meso-tetrahydrofurans, and Enantiospecific Ring-enlargement.
T. Katsuki,
Curr. Org. Chem., 5 (6), 663-678 (2001).

■Asymmetric Oxidation.　
香月　勗.
化学と教育, 49 (10), 643-646 (2001).

【2000年】

◆Enantioselective Epoxidation of Conjugated trans-Olefins with (Salen)manganese(III) Complexes as Catalysts.
H. Nishikori, C. Ohta, and T. Katsuki,
Synlett, 2000, 1557-1560.

◆Asymmetric Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by Photo-activated Chiral (NO)Ru(II)-salen Complex.
R. Irie, K. Masutani, and T. Katsuki,
Synlett, 2000, 1433-1436.

◆Enthalpy- and/or Entropy-controlled Asymmetric Oxidation: Stereocontrolling Factors in Mn-salen-Catalyzed Oxidation.
T. Nishida, A. Miyafuji, Y. N. Ito, and T. Katsuki,
Tetrahedron Lett., 41, 7053-7058 (2000).

◆Catalytic Asymmetric and Chemoselective Aerobic Oxidation: Kinetic Resolution of sec-Alcohols.
K. Masutani, T. Uchida, R. Irie, and T. Katsuki,
Tetrahedron Lett., 41, 5119-5123 (2000).

◆Short Step Enantioselective Synthesis of (-)-Swainsonine.
T. Punniyamurthy, R. Irie, and T. Katsuki,
Chirality, 12, 464-468 (2000).

◆Cis- and Enantio-selective Cyclopropanation with Chiral (ON⁺)Ru-salen Complex as a Catalyst.
T. Uchida, R. Irie, and T. Katsuki,
Tetrahedron, 56, 3501-3509 (2000).

◆Catalytic Asymmetrization of Racemic Dicyclopentadiene Derivatives by Using Chiral Copper(II) Catalyst.
Y. Kohmura and T. Katsuki,
Enantiomer, 5, 47-61 (2000).

◆Co(II)-Salen-Catalyzed Highly Cis- and Enantioselective Cyclopropanation.
T. Niimi, T. Uchida, R. Irie, and T. Katsuki,
Tetrahedron Lett., 41, 3647-3651 (2000).

◆Asymmetric Allylic Oxidation of Cycloalkenes Using a Tridentate Tris(oxazoline) Ligand as a Chiral Auxiliary.
Y. Kohmura and T. Katsuki,
Tetrahedron Lett., 41, 3941-3945 (2000).

◆Mn-salen Catalyzed Enantioselective Sulfimidation.
H. Nishikori and T. Katsuki,
Appl. Cat. A: General, 194, 475-477 (2000).

◆Application of Oxidative Desymmetrization of Meso-
Tetrahydrofurans: Synthesis of Functionalized Chiral Building Blocks and of (-)-Alloyohimbane.
A. Miyafuji, K. Ito, and T. Katsuki,
Heterocycles, 52, 261-272 (2000).

◆Catalytic Asymmetrization of Racemic Dicyclopentadiene Derivatives by Using Chiral Copper(II) Catalyst.
Y. Kohmura and T. Katsuki,
Enantiomer, 5 (1), 47-61 (2000).

■Asymmetric Epoxidation of Unfunctionalized Olefins and Related Reactions.
Katsuki, Tsutomu. Editor(s): Ojima, Iwao.
Catalytic Asymmetric Synthesis (2nd Edition) (2000), 287-325.

■Metallosalen-catalyzed Asymmetric Oxygen-transfer Reaction: Dynamics of Salen Ligand Conformation.
Katsuki, Tsutomu. Editor(s): Adam, Waldemar.
Peroxide Chemistry (2000), 303-319.

■Metallosalen-Catalyzed Asymmetric Oxygen-Transfer Reaction: Dynamics of Salen Ligand Conformation.
T. Katsuki
W. Adam ed., "Peroxide Chemistry", Wiley-VCH, pp. 303-319 (2000)

■Asymmetric Reactions Using Optically Active (Salen)ruthenium Complexes as Catalysts .
光学活性な(サレン)ルテニウム錯体を触媒に用いた不斉合成反応
香月　勗
化学と工業, 2000, 669-676.

■予断は禁物
香月　勗
有合化, 58, 405-407 (2000).

【1999年】

◆Conformational Analysis of Cationic (R,S)- and (R,R)-(Salen)manganese Complexes Possessing Axial Chirality as a Chiral Element Based on X-Ray Crystallography: An Explanation of the Effect of Apical Ligand on Enantioselection by (Salen)manganese Catalyst.
T. Hashihayata, T. Punniyamurthy, R. Irie, T. Katsuki, M. Akita, and Y. Moro-oka,
Tetrahedron, 55 (51), 14599-14610 (1999).

◆Highly Cis- and Enantioface-Selective Cyclpropanation Using (R,R)-Ru-Salen Complex: Solubility Dependent Enantioface Selection.
T. Uchida, R. Irie, and T. Katsuki,
Synlett, 1999, (11),1793-1795.

◆Asymmetric Allylic Alkylation Using a Palladium Complex of Chiral 2-(Phosphinoaryl)pyridine Ligands.
K. Ito, R. Kashiwagi, K. Iwasaki, and T. Katsuki,
Synlett, 1999, (10), 1563-1566.

◆Mn-salen Catalyzed Nitrene Transfer Reaction: Enantioselective Sulfimidation of Alkyl Aryl Sulfides.
H. Nishikori, C. Ohta, E. Oberlin, R. Irie, and T. Katsuki,
Tetrahedron, 55 (49), 13937-13946 (1999).

◆cis-Selective Aziridination of cis- and trans-α,β-Unsaturated Amides by Using Diaziridine.
K. Hori, H. Sugihara, Y. N. Ito, and T. Katsuki,
Tetrahedron Lett., 40, 5207-5210 (1999).

◆X-Ray Diffraction Analysis of Chiral (R,S)-(ON)Ru-Salen Complex: Unusual Unsymmetric Conformation.
T. Takeda, R. Irie, and T. Katsuki,
Synlett,1999, (7), 1166-1168.

◆Chiral (ON)Ru-Salen Catalyzed Cyclopropanation: High Cis- and Enantio-selecitvity.
T. Uchida, R. Irie, and T. Katsuki,
Synlett, 1999, (7), 1163-1165.

◆Photo-controlled Lewis Acidity: Chiral (ON)Ru-Salen Catalyzed Hetero-Diels-Alder Reaction and Kinetic Resolution of Racemic Epoxides.
J. Mihara, T. Hamada, T. Takeda, R. Irie, and T. Katsuki,
Synlett, 1999, (7), 1160-1162.

◆Ru-Salen Catalyzed Asymmetric Epoxidation: Photoactivation of Catalytic Activity.
T. Takeda, R. Irie, Y. Shinoda, and T. Katsuki,
Synlett, 1999, (7), 1157-1159.

◆Dynamic Control of Ligand Conformation: Asymmetric Epoxidation Using Achiral (Salen)manganese(III) Complex.
K. Miura and T. Katsuki,
Synlett, 1999, (6), 783-785.

◆Oxidative Asymmetrization of Racemic Alkenes: Asymmetric Synthesis of Optically Active Dicyclopentadiene Derivatives.
Y. Kohmura and T. Katsuki,
Synlett, 1999, (8), 1231-1234.

◆Why Do (R,R)- and (R,S)-(Salen)manganese(III) Complexes Show Different Substrate- Specificity? The Role of Apical Aqua Ligand.
T. Punniyamurthy, R. Irie, T. Katsuki, M. Akita, and Y. Moro-oka,
Synlett, 1999, (7), 1049-1052.

◆Asymmetric Desymmetrization of Meso-Pyrrolidine Derivatives by Enantiotopic Selective C-H Hydroxylation Using (Salen)manganese Complexes.
T. Punniyamurthy and T. Katsuki,
Tetrahedron, 55 (31), 9439-9454 (1999).

◆Catalytic Asymmetric [2,3]Sigmatropic Rearrangement: Co(III)-Salen Catalyzed S-Ylide Formation from Allyl Aryl Sulfides and Their　Rearrangement.
T. Fukuda, R. Irie, and T. Katsuki,　
Tetrahedron, 55 (3), 649-664 (1999).

■Asymmetric C-H Oxidation.
T. Katsuki,
In "Comprehensive Asymmetric Catalysis" ed by Jacobsen, E.N.; Pfaltz, A.; Yamamoto, H., Springer, Vol. II, Chap. 21. 791-802 (1999).

■サレン錯体触媒の新たな可能性：Ｃ−Ｈσ結合の不斉酸化と配位子配座の動的制御
香月　勗
有機合成化学協会誌, 57 (10), 824-834 (1999).

■Asymmetric Catalysis of New Generation Chiral Metallosalen Complexes.
Y. N. Ito and T. Katsuki,
Bull. Chem. Soc. Jpn., 72(4), 603-619 (1999).

■触媒的不斉酸化−直截的官能基導入法−
入江　亮, 香月　勗,
触媒, 41(3), 188-192 (1999).

■Epoxidation of Allylic Alcohols.
T. Katsuki,
In "Comprehensive Asymmetric Catalysis" ed by Jacobsen, E.N.; Pfaltz, A.; Yamamoto, H., Springer, Vol. II, Chap18.1. 621-648 (1999).

【1998年】

◆What is the Origin of High Asymmetric Induction by Chiral (Salen)manganese(III) Complex? Design of Comformationally Fixed Complex and Its Application to Asymmetric Epoxidation of 2,2-Dimethylchromenes.
Y. N. Ito and T. Katsuki,
Tetrahedron Lett., 39, 4325 (1998).

◆Kinetic Resolution of Racemic Allenes by Using (Salen)manganese(III) complex as a Catalyst.
Y. Noguchi, H. Takiyama, and T. Katsuki,
Synlett, 1998, 543.

◆A Short-Step Synthesis of trans-Whisky Lactone by an Asymmetric Michael Reaction.
H. Nishikori, K. Ito, and T. Katsuki,
Tetrahedron: Asymmetry, 9, 1165 (1998).

◆Highly Enantioselective Benzylic Hydroxylation with Concave Type of (Salen)manganese(III) Complex.
T. Hamada, R. Irie, J. Mihara, K. Hamachi, and T. Katsuki,
Tetrahedron, 54, 10017 (1998).

◆Asymmetric Desymmetrization of meso-Tetrahydrofuran Derivatives by Highly Enantiotopic Selective C-H Oxidation.
A. Miyafuji and T. Katsuki,
Tetrahedron, 54, 10339 (1998).

■サレン錯体を用いる不斉触媒反応.
入江　亮, 伊藤　芳雄, 香月　勗,
ファルマシア, 34 (4), 329-333 (1998).

■Titanium-Catalyzed Epoxidation.
T. Katsuki,
"Transition Metals for Organic Synthesis" ed by Bolm, C., Wiley-VCH, Volume II, 261(1998).

【1997年】

◆Benzylic and Allylic Amination.
Y. Kohmura, K. Kawasaki, and T. Katsuki,
Synlett, 1997, 1456.

◆Remarkable Solvent Effect on the Enantioface Selectivity in the Diels-Alder Reaction Catalyzed by the Aluminum Complex of Newly Prepared Chiral Menthol Derivative.
G. Naraku, K. Hori, Y. N. Ito, and T. Katsuki,
Tetrahedron Lett., 38, 8231 (1997).

◆A New Methodology for the Stereoselective Synthesis of 4-Substituted Butenolides: Asymmetric Michael Addition Reaction of 2-(Trimethylsilyloxy)furans to Oxazolidinone Enoates.
H. Kitajima, K. Ito, and T. Katsuki,
Tetrahedron, 53, 17015 (1997).

◆The First Asymmetric Epoxidation Using a Combination of Achiral (Salen)manganese(III) Complex and Chiral Amine,
T. Hashihayata, Y. Ito, and T. Katsuki,
Tetrahedron, 53, 9541 (1997).

◆Enantiotopic Place-Selective C-H Oxidation Using (Salen)manganese(III) Complex as a Catalyst.
A. Miyafuji and T. Katsuki,
Synlett, 1997, 836.

◆A New Enantiospecific Approach to the Bislactone Structure: Formal Syntheses of (-)-Avenaciolide and (-)-Isoavenaciolide.
K. Ito, T. Fukuda, and T. Katsuki,
Heterocycles, 46, 401 (1997).

◆Highly Enantioselective Cyclopropanation of Styrene Derivatives Using Co(III)-Salen Complex as a Catalyst.
T. Fukuda and T. Katsuki,
Tetrahedron, 53, 7201 (1997).

◆Enantioselective Allylic Oxidation of Cycloalkenes by Using Cu(II)-Tris(oxazolines) Complex as a Catalyst.
K. Kawasaki and T. Katsuki,
Tetrahedron, 53, 6337 (1997).

◆Co(III)-Salen Catalysed Carbenoid Reaction: Stereoselective [2,3]Sigmatropic Rearrangement of S-Ylide derived from Allyl Aryl Sulfides.
T. Fukuda and T. Katsuki,
Tetrahedron Lett, 38, 3443 (1997).

◆Chiral Lewis Acid Promoted Asymmetric Michael Addition Reaction of 2-(Trimethylsilyloxy)furans,
H. Kitajima and T. Katsuki,
Synlett, 1997, 568.

◆A New Methodology for Efficient Construction of 2,7-Dioxabicyclo[3.3.0]octane Derivatives.
K. Ito, T. Fukuda, and T. Katsuki,
Synlett, 1997, 387.

◆Unusual Solvent-Effect in Stereochemistry of Asymmetric Epoxidation Using a (Salen)chromium(III) Complex as a Catalyst.
H. Imanishi and T. Katsuki,
Tetrahedron Lett., 38, 251 (1997).

◆N,N,N',N'-Tetraalkyl-2,2'-dihydroxy-1,1'-binaphthyl-3,3'-dicarboxamides: Novel Chiral Auxiliaries for Asymmetric Simmons-Smith Cyclopropanation of Allylic Alcohols and for Asymmetric Diethylzinc Addition to Aldehydes.
H. Kitajima, K. Ito, Y. Aoki, and T. Katsuki,
Bull. Chem. Soc. Jpn. 70, 207 (1997).

■Asymmetric Reactions Using Metallosalen Complexes as Catalysts.
T. Katsuki,
Recent Res. Devel in Pure & Applied Chem., 1, 35-44 (1997).

■カルベノイド反応の新展開：新たな不斉合成反応の開発に向けて.
伊藤克治, 福田　勉, 北嶋　浩, 香月　勗,
有機合成化学協会誌, 55 (9), 764-773 (1997).

【1996年】

◆Catalytic and Highly Enantioselective Aziridination of Styrene Derivatives.
H. Nishikori and T. Katsuki,
Tetrahedron Lett., 37, 9245 (1996).

◆Enantioselective Epoxidation of 2,2-Dimethylchromenes Using Achiral Mn-Salen Complex as a Catalyst in the Presence of Chiral Amine.
T. Hashihayata, Y. Ito, and T. Katsuki,
Synlett, 1996, 1079.

◆Highly Enantioselective Catalytic Oxidation of Alkyl Aryl Sulfides with Mn-Salen Catalyst.
C. Kokubo and T. Katsuki,
Tetrahedron, 52, 13895 (1996).

◆Asymmetric Benzylic Oxidation Using Mn-Salen Complex as a Catalyst.
K. Hamachi, R. Irie, and T. Katsuki,
Tetrahedron Lett., 37, 4979 (1996).

◆Mn-Salen Catalyzed Asymmetric Epoxidation of (±)-3-Alkylindene: Reagent-Dependent Stereoselectivity.
Y. Noguchi, R. Irie, T. Fukuda, and T. Katsuki,
Tetrahedron Lett., 37, 4533 (1996).

◆Mn-Salen Catalyzed Asymmetric Oxidation of Enol Derivatives.
T. Fukuda and T. Katsuki,
Tetrahedron Lett., 37, 4389 (1996).

◆Enantioselective Addition of Diethylzinc to Aldehydes Using 1,1'-Bi-2-naphthol-3,3'-dicarboxamide as a Chral Auxiliary.
H. Kitajima, K. Ito, and T. Katsuki,
Chem. Lett., 1996, 343.

◆Chiral Biquinoline and Bipyrindine Ligands: Their Asymmetric Synthesis and Application to the Synthesis of trans-Whisky Lactone.
K. Ito, M. Yoshitake, and T. Katsuki,
Tetrahedron, 52, 3905 (1996).

◆Mechanism of One Oxygen Atom Transfer from Oxo(salen)manganese(V) Complex to Olefins.
T. Hamada, T. Fukuda, H. Imanishi, and T. Katsuki,
Tetrahedron, 52, 515 (1996).

◆Enantiospecific Ring Expansion of Oxetanes: Stereoselective Synthesis of Tetrahydrofurans from Oxetanes.
K. Ito, M. Yoshitake, and T. Katsuki,
Heterocycles, 42, 305 (1996).

■Asymmetric Epoxidation of Allylic Alcohols-The Katsuki-Sharpless Asymmetric Epoxidation.
T. Katsuki and V. S. Martin
Org. React., 48, 1-299 (1996).

■Mn-Salen Catalyst, Competitor of Enzymes, for Asymmetric Epoxidation.
T. Katsuki,
J. Mol. Cat. A, 113, 87-107 (1996).

【1995年】

◆Enantioselective Allylic Oxidation Using Biomimetic Tris(oxazolines)-Copper(II) Complex.
K. Kawasaki, S. Tsumura, and T. Katsuki,
Synlett, 1995, 1245.

◆Asymmetric Simmons-Smith Cyclopropanation of E-Allylic Alcohols Using 1,1'-Bi-2-naphthol-3,3'-dicarboxamide as a Chiral Auxiliary,
H. Kitajima, Y. Aoki, K. Ito, and T. Katsuki,
Chem. Lett., 1995, 1113.

◆Enantioselective Synthesis of trans-Whisky Lactone by Using Newly Developed Asymmetric Ring Expansion Reaction of Oxetane as a Key Step.
K. Ito, M. Yoshitake, and T. Katsuki,
Chem. Lett., 1995, 1027.

◆Insect Pheromone Synthesis Using Mn-Salen Catalyzed Asymmetric Epoxidation as a Key Step.
T. Hamada, K. Daikai, R. Irie, and T. Katsuki,
Tetrahedron: Asymmetry, 6, 2441 (1995).

◆Asymmetric Diels-Alder Reaction Using Oxo(salen)manganese(V) Complex as a Lewis Acid Catalyst.
Y. Yamashita and T. Katsuki,
Synlett, 1995, 829.

◆Mn-Salen Catalyzed Asymmetric Epoxidation of 1,3-Cycloalkadienes and Dialkylsubstituted Z-Olefins.
D. Mikame, T. Hamada, R. Irie, and T. Katsuki,
Synlett, 1995, 827.

◆Co(III)-Salen Catalyzed Asymmetric Cyclopropanation.
T. Fukuda and T. Katsuki,
Synlett, 1995, 825.

◆Borane O-Adduct Can Be an Intermediate in Chiral N-Sulfonyloxazaborolidine-Catalyzed Enantioselective Reduction of Ketones.
K. Otsuka, K. Ito, and T. Katsuki,
Synlett, 1995, 429.

◆Enantioselective Synthesis of Macrolide Pheromones, (5Z,13S)-5-Tetradecen-13-olide and (9R)-decan-9-olide, by Using Mn-Salen Catalyzed Asymmetric Epoxidation as a Key Step.
T. Hamada, K. Daikai, R. Irie, and T. Katsuki,
Synlett, 1995, 407.

◆Enantioselective Synthesis of Macrolide Pheromones, (5Z,13S)-5-Tetradecen-13-olide and (9R)-decan-9-olide, by Using Mn-Salen Catalyzed Asymmetric Epoxidation as a Key Step.
T. Hamada, K. Daikai, R. Irie, and T. Katsuki,
Synlett, 1995, 407.

◆Synthesis of Mn-Salen Catalyst Bearing (1R,2R,3R,6R)-3,6-Dimethylcylohexane-1,2-diamine as an Ethylenediamine Part and Its Application to Asymmetric Epoxidation.
T. Kuroki, T. Hamada, and T. Katsuki,
Chem. Lett., 1995, 339.

◆Synthesis of a New Chiral Auxiliary, (1R,2R,3R,6R)-3,6-Dimethylcylohexane-1,2-diamine.
T. Kuroki and T. Katsuki,
Chem. Lett., 1995, 337.

◆Mn-Salen Catalyzed Asymmetric Epoxidation of Conjugated Trisubstituted Olefins.
T. Fukuda, R. Irie, and T. Katsuki,
Synlett, 1995, 197.

■Mn-Salen Catalyzed Asymmetric Oxidation of Simple Olefins and Sulfides.
T. Katsuki,
J. Synth. Org. Chem., 53 (11), 940-951 (1995).

【1994年】

◆Asymmetric Carbene C-O Insertion Reaction Using Optically Active Bipyridine-Copper Complex as a Catalyst: Ring Expansion of Oxetanes to Tetrahydrofurans.
K. Ito and T. Katsuki,
Chem. Lett., 1994, 1857.

◆Effect of Vicinal Polar Group on the Ortho-Directing Ability of 1,3-Dimethylimidazoline.
E. Tamura, K. Kawasaki, D. Mikame, and T. Katsuki,
Mem. Fac. Sci., Kyushu Univ., C, Chem., 19, 115 (1994).

◆Effect of Directing Group in Ortho Lithiation Changes with Its Vicinal Group.
E. Tamura, K. Kawasaki, D. Mikame, and T. Katsuki,
Synlett, 1994, 609.

◆Rational Design of Mn-Salen Catalyst (2): Highly Ensantioselective Epoxidation of Conjugated cis-Olefins.
H. Sasaki, R. Irie, T. Hamada, K. Suzuki, and T. Katsuki,
Tetrahedron, 50, 11827 (1994).

◆Catalytic Asymmetric Oxidation of Sulfides Using (Salen)manganese(III) Complex as a Catalyst.
K. Noda, N. Hosoya, R. Irie, Y. Yamashita, and T. Katsuki,
Tetrahedron, 50, 9609 (1994).

◆How Does Chiral Oxo(salen)manganese(V) Complex Discriminate the Enantioface of Simple Olefins? Scope and Limitation of Salen-Catalyzed Epoxidation,
T. Hamada, R. Irie, and T. Katsuki,
Synlett, 1994, 479.

◆Construction of Highly Efficient Mn-Salen Catalyst for Asymmetric Epoxidation of Conjugated cis-Olefins.
H. Sasaki, R. Irie, and T. Katsuki,
Synlett, 1994, 356.

◆Enantioselective Epoxidation of Chromene Derivatives Using Hydrogen Peroxide as a Terminal Oxidant.
R. Irie, N. Hosoya, and T. Katsuki,
Synlett, 1994, 255.

◆Asymmetric Oxidation of Sulfides Using (Salen)manganese(III) Complex As a Catalyst.
K. Noda, N. Hosoya, K. Yanai, R. Irie, and T. Katsuki,
Tetrahedron Lett., 35, 1887 (1994).

◆Rational Design of Mn-Salen Epoxidation Catalysts: Preliminary Results.
N. Hosoya, A. Hatayama, R. Irie, H. Sasaki, and T. Katsuki,
Tetrahedron, 50, 4311 (1994).

【1993年】

◆Chiral Leaving Group: Synthesis of Optically Active Benzimidazole and Its Application to Asymmetric Acylation.
M. Ogata, T. Yoshimura, H. Fujii, Y. Ito, and T. Katsuki,
Synlett, 1993, 728.

◆A Formal Synthesis of Aplysiatoxin: Enantioselective Synthesis of Kishi's Aldehyde.
H. Okamura, S. Kuroda, S. Ikegami, K. Tomita, Y. Sugimoto, S. Sakaguchi, Y. Ito, T. Katsuki, and M. Yamaguchi,
Tetrahedron, 49, 10531 (1993).

◆Asymmetric Epoxidation with Optically Active (Salen)manganese(III) complexes. From Which Direction Does Olefin Approach Metal-Oxo Bond?
N. Hosoya, A. Hatayama, K. Yanai, H. Fujii, R. Irie, and T. Katsuki,
Synlett, 1993, 641.

◆Catalytic Asymmetric Reduction of Acetophenone Using Optically Active N-sulfonyloxazaborolidine as a Catalyst.
K. Otsuka, K. Ito, and T. Katsuki,
Mem. Fac. Sci., Kyushu Univ., C, Chem., 19, 23 (1993).

◆Asymmetric Cyclopropanation of E-olefins Using Copper Complex of Optically Active Bipyridine As a Catalyst.
K. Ito and T. Katsuki,
Synlett, 1993, 638.

◆Catalytic Asymmetric Cyclopropanation Using Copper Complex of Optically Active Bipyridine as a Catalyst.
K. Ito and T. Katsuki,
Tetrahedron Lett., 34, 2661 (1993).

◆Asymmetric Aziridination by Using Optically Active (Salen)manganese(III) Complexes.
K. Noda, N. Hosoya, R. Irie, Y. Ito, and T. Katsuki,
Synlett, 1993, 469.

◆Catalytic Asymmetric Epoxidation with (Salen)manganese(III) Complex Bearing Binaphthyl Groups of Axial Chirality.
H. Sasaki, R. Irie, and T. Katsuki,
Synlett, 1993, 300.

◆Construction of New Opyically Active (Salen)manganese Complexes and their Application to Asymmetric Epoxidation of Styrene Derivatives.
N. Hosoya, R. Irie, and T. Katsuki,
Synlett, 1993, 261.

【1992年】

◆A Mechanistic Insight into the Aerobic Epoxidation Catalyzed by Nickel Complexes under the Mukaiyama's Conditions.
K. Yanai, R. Irie, Y. Ito, and T. Katsuki,
Mem. Fac. Sci., Kyushu Univ., C, Chem., 18, 213 (1992).

◆Catalytic Epoxidation Using Binuclear Metal Complexes as Catalysts.
T. Oda, R. Irie, T. Katsuki, and H. Okawa,
Synlett, 1992, 641.

◆Stereoselective Synthesis of (ア)-Ireland Alcohol Using Titanium-Mediated [2,3]Wittig Rearrangement Product as a Starting Material.
S. Ikegami, H. Okamura, S. Kuroda, T. katsuki, and M. Yamaguchi,
Bull. Chem. Soc. Jpn., 65, 1841 (1992).

◆Synthesis of New Chiral Bipyridine Complexes and Its Application to Asymmetric Cyclopropanation.
K. Ito, S. Tabuchi, and T. Katsuki,
Synlett, 1992, 575.

◆Enantioselective Addition of Diethylzinc to Aldehydes in the Presence of Chiral Titanium reagent Modified with N-Sulfonylated Amino Alcohol.
K. Ito, Y. Kimura, H. Okamura, and T. Katsuki,
Synlett, 1992, 573.

◆Highly Enantioselective Epoxidation of 2,2-Dimethylchromenes.
A. Hatayama, N. Hosoya, R. Irie, Y. Ito, and T. Katsuki,
Synlett, 1992, 407.

◆CD Spectral Diagnosis of Absolute Configuration of Tetrahedral or Pseudo-terahedral Salicylideneiminate Complexes.
H. Sakiyama, H. Okawa, N. Oguni, T. Katsuki, and R. Irie,
Bull. Chem. Soc. Jpn., 65, 606 (1992).

【1991年】

◆Catalytic Epoxidation with Molecular Oxygen using Nickel Complex.
R. Irie, Y. Ito, and T. Katsuki,
Tetrahedron Lett., 32, 6891 (1991).

◆Kinetic Resolution of dl-Epoxy Alcohols Using Chiral Titanium Complex with Amino Acid Derived Ligand.
A. Ishikawa and T. Katsuki,
Tetrahedron Lett., 32, 3547 (1991).

◆Enantioselective Epoxidation of Olefins by Using (Salen)manganese(III) Complexes Bearing 4-Methyl-3-[(R)-1-phenylpropyl]salicylaldehyde as a Chiral Constituent.
N. Hosoya, R. Irie, Y. Ito, and T. Katsuki,
Synlett, 1991, 691.

◆Catalytic Asymmetric Epoxidation of Unfunctionalized Olefins Using Chiral (Salen)manganese(III) Complexes.
R. Irie, K. Noda, Y. Ito, N. Matsumoto, and T. Katsuki,
Tetrahedron: Asymmetry, 2, 481 (1991).

◆Donor Ligand Effect in Enantioselective Epoxidation of Unfunctionalized Olefins Using Chiral (Salen)manganese(III) Complexes.
R. Irie, Y. Ito, and T. Katsuki,
Synlett, 1991, 265.

◆A Formal Total Synthesis of Aplysiatoxin.
H. Okamura, S. Kuroda, S. Ikegami, Y. Ito, T. Katsuki, and M. Yamaguchi,
Tetrahedron Lett., 32, 5141 (1991).

◆Synthesis of Aplysiatoxin: Stereoselective Synthesis of Key Fragments.
H. Okamura, S. Kuroda, K. Tomita, S. Ikegami, Y. Sugimoto, S. Sakaguchi, T. Katsuki, and M. Yamaguchi,
Tetrahedron Lett., 32, 5137 (1991).

◆Enantioselective Epoxidation of Unfunctionalized Olefins Using Chiral (Salen)manganese(III) Complexes.
R. Irie, K. Noda, Y. Ito, and T. Katsuki,
Tetrahedron Lett., 32, 1055 (1991).

【1990年】

◆Catalytic Asymmetric Epoxidation of Unfunctionalized Olefins.
R. Irie, K. Noda, Y. Ito, N. Matsumoto, and T. Katsuki,
Tetrahedron Lett., 31, 7345 (1990).

◆Stereoelectronically Controlled [2,3]Wittig Rearrangement of Isopropyl 2'-Heterosubstituted-2'-alkenyloxyacetates.
A. Ishikawa, H. Uchiyama, T. Katsuki, and M. Yamaguchi,
Tetrahedron Lett., 31, 2415 (1990).

◆Stereoselective Construction of Acyclic Structures with Four Consecutive Asymmetric Centers.
T. Hanamoto, T. Katsuki, and M. Yamaguchi,
Bull. Chem. Soc. Jpn., 63, 1039 (1990).